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{#vc_header_5e1f0a008ae83926 .header_subtitle{font-size:20px !important;}}</style> <div class="qfe_wrapper"> <h1 class="qfy_title left mobileleft"> <div class="qfy_title_inner" style="display:inline-block;position:relative;max-width:100%;"> <div class="header_title" style="font-family:微軟雅黑;font-size:26px;font-weight:normal;font-style:normal;color:#191919;"> TP超標被罰29萬，遭遇總磷超標怎么應急？ </div> </div> </h1> </div> </div> <div m-padding="0px 0px 0px 0px" p-padding="0 0 0 0" css_animation_delay="0" qfyuuid="qfy_column_text_mtoeb-c-9c" data-anitime="0.7" class="qfy-element qfy-text qfy-text-68107 qfe_text_column qfe_content_element newsdate " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:0;margin-bottom:20px;padding-top:0;padding-bottom:0;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <div><span style="" class="qfy_no_editor pdate">2022/3/3</span></div> </div> </div> <div m-padding="0px 0px 70px 0px" p-padding="0 0 70px 0" css_animation_delay="0" qfyuuid="qfy_column_text_re2wu-c-9c" data-anitime="0.7" data-ani_iteration_count="1" class="qfy-element qfy-text qfy-text-85363 qfe_text_column qfe_content_element " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:10px;margin-bottom:0;padding-top:0;padding-bottom:70px;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">2022年3月1日，江蘇徐州市生態環境局公布了一起查處的違法排污案件，徐州市銅山區柳新鎮污水處理廠因超標排放水污染物被處罰！</span></p><p><section><p style="text-align: center; line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 16px; box-sizing: border-box !important; overflow-wrap: break-word !important;">徐州市生態環境局</span></strong><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-size: 16px; box-sizing: border-box !important; overflow-wrap: break-word !important;">行政處罰決定書</span></strong></span></p><p style="text-align: center; line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="color: rgb(0, 0, 0); margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: center; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">徐環港罰決字〔2021〕11號</span></strong></span></p></section></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">一、調查情況及發現的環境違法事實、證據和陳述申辯（聽證）及采納情況：</span></strong></span></p><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">我局于2021年10月14日對你公司進行了調查，發現你公司實施了以下環境違法行為：</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">現場檢查時你廠正在運行，我局委托江蘇方正環保集團有限公司在該廠污水進水口、污水排放口各取水樣3000毫升經封存后帶回實驗室進行檢測。2021年10月20日檢測報告顯示該廠污水排放口化學需氧量24mg/L、氨氮0.294mg/L、總磷0.75mg/L、總氮12.3mg/L、懸浮物27mg/L，對照該廠排污許可證要求，檢測結果顯示該廠污水排放口總磷和懸浮物濃度超過排污許可證上污染物排放限值。</span></p></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">以上事實有以下在卷證據為憑：</span></p><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">1.2021年10月14日徐州市生態環境局淮海國際港務區分局行政執法人員在你公司檢查時做的現場檢查(勘查)筆錄，證明你公司存在的違法事實。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">2.2021年10月25日和2021年11月04日徐州市生態環境局淮海國際港務區分局行政執法人員關于你公司檢查的調查詢問筆錄，證明你公司存在的違法事實。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">3.現場檢查取證證據（照片）、現場視頻資料、環境檢測報告、你公司排污許可證復印件，證明你公司存在的違法事實。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">4.營業執照(副本)復印件、授權委托書、受委托人身份證復印件、法律文書送達地址確認書確定違法主體。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">以上證據形成了完整的證據鏈，證明你公司違法事實清楚，證據確鑿。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">你公司的上述行為違反了《中華人民共和國水污染防治法》第五十條第二款“城鎮污水集中處理設施的運營單位，應當對城鎮污水集中處理設施的出水水質負責。環境保護主管部門應當對城鎮污水集中處理設施的出水水質和水量進行監督檢查?！敝幎?。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">我局于2021年12月02日對你公司下達《行政處罰事先（聽證）告知書》（徐環港罰告字〔2021〕11號）告知你公司擬作出行政處罰決定的事實、理由及依據，并告知你公司依法享有陳述權、申辯權及聽證申請權。你公司于2021年12月03日提交聽證申請書，我局于2021年12月21日召開聽證會，聽證會上你公司提出：一、處罰決定取證程序違法。1、行政處罰的證據《檢測報告》未依法告知申辯人。2、取樣檢測程序違法，應按《城鎮污水處理廠污染物排放標準》（GB18918-2002）取24h混合樣，瞬時數據不能作為處罰依據。二、關于法律適用問題。不能簡單的引用《關于環保部門現場檢查中排污監測方法問題的解釋》，環保部門應在執法中嚴格遵循國家標準及地方標準。三、關于處罰適當性。依據《行政處罰法》第五條和第六條規定，本案處罰過重，違反公平、公正原則。我局認為：你公司提出取證程序違法，經對調查取證進行復核，執法人員取證程序符合《行政處罰法》及《環境行政處罰辦法》等相關規定。對你公司違法行為擬處罰金額，是考慮違法行為超標因子以及超標倍數等各違法情節，依據法律規定并參考《江蘇省生態環境行政處罰裁量基準規定》作出，處罰金額適當。你公司未有證據證實簽字時取樣記錄表為空白，同時檢測報告亦符合《環境行政處罰辦法》第三十五條的載明事項要求，檢測報告可以作為行政處罰依據。綜上所述，執法人員擬作出的行政處罰證據確鑿，適用法律、法規正確，處罰金額在法定范圍內，根據省自由裁量規定進行裁量，符合法律規定。因此，你公司的陳述申辯理由我局不予采納。</span></p></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">二、行政處罰的依據、種類：</span></strong></span></p><p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">依據《中華人民共和國水污染防治法》第八十三條第一款第二項“違反本法規定，有下列行為之一的，由縣級以上人民政府環境保護主管部門責令改正或者責令限制生產、停產整治，并處十萬元以上一百萬元以下的罰款；情節嚴重的，報經有批準權的人民政府批準，責令停業、關閉：（二）超過水污染物排放標準或者超過重點水污染排放總量控制指標排放水污染物的；”之規定，適用行政處罰裁量基準：《江蘇省生態環境行政處罰裁量基準規定》（表7-1）。經我局案件審查委員會研究決定，對你公司作出如下行政處罰：</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(171, 25, 66);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; box-sizing: border-box !important; overflow-wrap: break-word !important;">處罰款貳拾玖萬元整（29萬元）；</span></strong></span></span><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 15px; letter-spacing: 2px;"> </span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">同時依據《中華人民共和國行政處罰法》第二十八條第一款“行政機關實施行政處罰時，應當責令當事改正或者限期改正違法行為?！敝幎?，責令你公司立即改正違法行為。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">三、處罰決定履行方式及期限：</span></strong></span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">對于行政處罰，根據《中華人民共和國行政處罰法》和《罰款決定與罰款收繳分離實施辦法》的規定，限你公司于接到本處罰決定之日起15日內至我局財務室（市行政中心東三區445房間）開具繳款通知書，并按照財務規定繳納罰款。逾期不繳納罰款的，我局將每日按罰款數額的3％加處罰款，加處罰款最高不超過本金。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">四、申請行政復議或者提起行政訴訟的途徑和期限：</span></strong></span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">如不服本處罰決定，可在收到本處罰決定書之日起六十日內向徐州市人民政府申請行政復議，也可以在六個月內向徐州鐵路運輸法院提起行政訴訟。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">申請行政復議或者提起行政訴訟，不停止行政處罰決定的執行。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">逾期不申請行政復議，不提起行政訴訟，又不履行本處罰決定的，我局將依法申請人民法院強制執行。</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">（此件一式二份，一份存檔，一份送達當事人）</span></p><p style="line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></span></p><p style="text-align: right; line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">徐州市生態環境局（印章）</span></p><p style="text-align: right; line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;">2022年2月28日</span></p><p style="text-align: right; line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></span></p><p style="text-align: center; line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: inherit; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 20px; letter-spacing: 2px; text-align: center; white-space: normal; background-color: rgb(239, 112, 96); border-color: rgb(239, 112, 96); box-sizing: border-box !important; overflow-wrap: break-word !important;">總磷超標怎么應急？</strong><br/></span></p><p style="text-align: left; line-height: 2em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px; font-family: 微軟雅黑, "Microsoft YaHei"; box-sizing: border-box !important; overflow-wrap: break-word !important;"><section>在生化除磷達不到排放要求時，應及時迅速的投加化學藥品來協助除磷——化學除磷，可以用我們一定有的鋁鹽（例如PAC）或者鐵鹽（例如PFS）來應急，這兩種都是很好的除磷劑！本文中的TP僅限于正磷酸鹽！<br/></section><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">1、鋁鹽和鐵鹽為什么可以應急？</strong></section><section><section>化學除磷主要是通過化學沉析過程完成的，化學沉析是指通過向污水中投加無機金屬鹽藥劑與污水中溶解性的鹽類（如磷酸鹽）反應生成顆粒狀、非溶解性的物質。實際上投加化學藥劑后，污水中進行的不僅是沉析反應，同時還發生著化學絮凝作用，即形成的細小的非溶解狀的固體物互相粘結成較大形狀的絮凝體。</section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">污水沉析反應可以簡單的理解為：水中溶解狀的物質，大部分是離子狀物質轉換為非溶解、顆粒狀形式的過程，絮凝則是細小的非溶解狀的固體物互相粘結成較大形狀的過程，所以絮凝不是相轉移過程。絮凝是用于改善沉淀池的沉淀效果，而沉析則用于污水中溶解性磷的去除。</span></section><section><section>鋁鹽除磷方程式：</section><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">Al2(SO4)3+6H2O----2Al(OH)3+3SO42-+6CO2</strong></section><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: center; white-space: normal; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">Al2(SO4)3+2PO4----2AlPO4+3SO42-</strong></strong></section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">在pH為6.0-6.5的條件下，每1mol的磷需要加鋁1.5-3.0mol。如果水顯堿性，在加鋁之前應先降低pH以減少Al(OH)3沉淀。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">鐵鹽除磷方程式：</span></section><section><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">Fe2(SO4)3+3HCO3----Fe(OH)3+2SO42-+3CO2</strong></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">每1mol磷需要加鐵（Fe3+)1.5-3mol，最佳pH為5.0。</span></section><section><section>對磷含量為5mg/l左右的二級處理水，通過投加100－200mg/l的氯化鐵（FeCl3.6H2O)就可以得到90％以上的磷去除率。</section><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">2、鋁鹽和鐵鹽投加量的計算</strong></section><section><section>去除一分子的磷酸鹽，需要一分子的鐵鹽或者鋁鹽。為了計算方便，實際計算采用克分子(mol)或者克原子量。</section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">在化學沉析除磷時，去除lmol(31g)P至少需要lmol(56g)Fe，或者至少需要1.8(56/31)倍的Fe，或者O.9(27/31)倍的Al。也就是說去除lgP至少需要1.8g的Fe，或者0.9g的Al。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">由于在實際中，反應中并不是100%有效進行的，加之OH-會與金屬離子競爭反應，生成相應的氫氧化，所以實際化學沉析藥劑投加一般需要超量投加，以保證達到所需要的出水P濃度。德國在計算時，提出了投加系數β的概念，即：</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; color: rgb(171, 25, 66); box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">β=(molFe,molAl)／molP</strong></span></section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255);">投加系數β是受多種因素影響的，如投加地點、混合條件等，實際投加時建議通過投加試驗確定，圖5是投加系數和磷減少量的關系。在最佳條件下(適宜的投加、良好的混合和絮凝體的形成條件)β=1；在非最佳條件下，β=2到3或更高。過量投加藥劑不僅會使藥劑費增加，而且因氫氧化物的大量形成也會使污泥量大大增加，這種污泥體積大、難脫水。</span></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><img src="/admin888/ueditor/asp/upload/image/20220303/16462775864435255.png" title="image.png" alt="image.png"/></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><section>德國在實際計算中，為了有效地去除磷(出水保持＜1mgP/1)，β值為1.5，也就是說去除1kg磷，需要投加：</section><section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; color: rgb(171, 25, 66); box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">1.5×（56／31）=2.7 kg Fe<section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; color: rgb(171, 25, 66); box-sizing: border-box !important; overflow-wrap: break-word !important;">或者，</span></section></strong></span></section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(171, 25, 66); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: center; white-space: normal; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;">1.5×（27／31）=1.3 kg Al</strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 15px; letter-spacing: 2px; text-align: justify; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><h2 style="margin: 0px; padding: 0px; outline: 0px; font-weight: 400; font-size: 16px; max-width: 100%; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="font-size: 15px; font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(171, 25, 66); letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">計算舉例</strong></span></h2><p></p><section>例：污水處理廠設計水量為10000m3/d，進水中的P濃度為14mg/1，出水P濃度要求達到1mg/l。試計算所需要的藥劑量。<br/></section><p><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">解：</strong></section><section>經過初次沉淀地沉淀處理后去除的磷為2mg/l，則生物處理設施進水的P濃度為11mg/l，經過生物同化作用去除的P為1mg/l。則需經沉析去除的：<br/></section><section>P負荷=10000m3/d·(0.011-0.001)kg/m3=100kg/d</section></p><section>設計采用投加系數β值為1.5，</section><p><section>設計Al的投加量為：1.5×（27／31）×100=130kgAl/d</section><section>設計Fe的投加量為：1.5×（56／31）×100=271kgFe/d</section></p></span></section></section></section></section></section></span></p></p> </div> </div> <div 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